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Recent developments in speleothem science are showing their potential for paleofire reconstruction through a variety of inorganic and organic proxies including trace metals (1) and the pyrogenic organic compound levoglucosan (2). Previous work by Argiriadis et al. (2019) presented a method for the analysis of trace polycyclic aromatic hydrocarbons (PAHs) and n-alkanes in stalagmites (3). These compounds reflect biogeochemical processes occurring at the land surface, in the soil, and in the cave. PAHs are primarily related to combustion of biomass while n-alkanes, with their potential for vegetation reconstruction (4), provide information on fuel availability and composition, as well as fire activity. These organic molecules are carried downward by infiltrating water and incorporated into speleothems (5), thereby creating the potential to serve as novel paleofire archives.
Using this approach, we developed a high-resolution stalagmite record of paleofire activity from